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Síntese de furanos trissubstituídos via reações de oxopaladação aeróbica
(Universidade Federal de São Carlos, 2019-02-25)
Furans are important heterocyclics with broad application in synthesis as a building block, frequently presented in a wide range of compounds that exhibit biological activity, including natural products. Intramolecular ...
Acilação e alquilação fotoquímica de heteroarenos utilizando diacetil
(Universidade Federal de São Carlos, 2018-11-01)
N-heterocycles are important building blocks in the synthesis of bioactive compounds, besides that many of them are present in natural products. Most of the methodologies for heteroarene functionalization requires several ...
Influência do grupo carboxílico na atividade citotóxica e na interação de novos complexos de rutênio com DNA e HSA
(Universidade Federal de São Carlos, 2016-02-25)
The purpose of this work is evaluate how the position of a free carboxyl group can affect the interaction with DNA and HSA, and the cytotoxic profile against tumor and normal cells and Mycobacterium tuberculosis, for a set ...
Avaliação de diferentes estratégias de determinação de nutrientes e potenciais contaminantes em alimentos por técnicas baseadas em laser
(Universidade Federal de São Carlos, 2018-10-19)
The present project focuses on the development of strategies for the elemental determination of Ca, Cd, Cr, Cu, Fe, Mg, Pb and Zn in samples of orange juice and dietary supplements by Laser-Induced Breakdown Spectroscopy ...
Estudo químico e ecológico de Escovopsis spp., invasor do jardim de fungos de formigas cortadeiras
(Universidade Federal de São Carlos, 2018-05-02)
Microorganisms associated to leaf cutting ants comprise an important source of antifungal and antibacterial compounds due to the environment they are inserted in. The fungal garden is composed by a complex microbial network ...
Avaliação do uso de laser-induced breakdown spectroscopy (LIBS) e wavelength dispersive x- ray fluorescence (WDXRF) na análise direta de couros naturais e sintéticos
(Universidade Federal de São Carlos, 2018-10-01)
The aim of this doctoral thesis was the development of analytical procedures for the qualitative and quantitative analysis of leather samples using LIBS and WDXRF techniques for direct analysis of solid samples. The first ...
Produção de haloalcaloides por fungos de ambiente terrestre
(Universidade Federal de São Carlos, 2016-09-02)
The production of secondary metabolites by microorganisms is a tool to find new substances with potential pharmacological activities of human interest. Thus, the search for more extreme environments or even exposure of ...
Avaliação morfológica, microestrutural e eletroquímica da liga Ti-6Al-4V soldada por fricção linear
(Universidade Federal de São Carlos, 2018-07-20)
MORPHOLOGICAL, MICROSTRUCTURAL, AND ELECTROCHEMICAL EVALUATION OF THE Ti-6Al-4V ALLOY WELDED BY FRICTION STIR WELDING - Reprocessing is an important step in the nuclear fuel cycle and basically consists of dissolving the ...
Adição de Michael de α,α-Diciano-Olefinas a Chalconas via organocatálise assimétrica empregando solvente derivado de biomassa
(Universidade Federal de São Carlos, 2018-05-18)
In recent years, organocatalysed reactions have become an important field in asymmetric synthesis. Particularly, Michael addition reactions using various donors and acceptors have been explored to generate substrates that ...
Estudo das propriedades estruturais, ópticas e fotoluminescentes do Sistema α-(Ag2-3x-yTRxLiy)WO4 (TR = Pr, Sm, Eu, Tb, Dy e Tm)
(Universidade Federal de São Carlos, 2018-08-17)
Luminescent materials of different colors emission are of great interest for development of new or more efficient optical devices. Although many materials have been reported using different approaches, green synthesis and ...