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Hidrotalcitas multimetálicas para produção de gás de síntese a partir do biogás
(Universidade Federal de São Carlos, 2015-03-18)
In this work, catalysts derived from hydrotalcites were employed in Direct Reforming of Biogas, once they feature the necessary basicity to allow and improve carbon removal during reforming. As a differential study, the ...
Catalisadores derivados de óxidos do tipo perovskita LaMO3, LaMFeO3 e LaMO3/γ-Al2O3 (M = Co, Ni ou Fe) aplicados à reforma a vapor de etanol
(Universidade Federal de São Carlos, 2014-07-30)
The hydrogen production has been extensively studied as a clean and powerful energy source, indicating that in the future hydrogen will became a key component for the global energy production, since burning fossil fuels, ...
Sobre a estabilidade de catalisadores de cobalto suportados durante a reforma do etanol
(Universidade Federal de São Carlos, 2012-06-11)
Cobalt-based catalysts supported on γ-alumina and magnesium aluminate modified with lanthanum and cerium have been applied to various conditions of reforming of ethanol. The initial challenge was to control the rate ...
Nanopartículas de Co suportadas em SiO2: síntese, caracterização e propriedades catalíticas para a reforma a vapor do etanol
(Universidade Federal de São Carlos, 2007-03-16)
Colloidal Co Nanoparticles (Co-NPs) were used to prepare supported Co catalysts. The Co-
NPs were obtained by thermal decomposition of the precursor Co2(CO)8 in the presence of
oleic acid and trioctylphosphine oxide ...
Hidrotalcitas de Ni-Mg-Al como precursores de catalisadores para produção de gás de síntese a partir de biogás
(Universidade Federal de São Carlos, 2010-07-29)
Catalysts obtained by thermal decomposition of the precursors with hydrotalcite-like structure [Mg1-xAlx (OH)2]x+ [CO3]x/n. mH2O and [Ni1-x Mg1-xAlx (OH)2]x+ [CO3]x/n. mH2O were prepared, characterized and tested in the ...
Efeito das condições de preparação da [CTA+]-SiMCM-41 na atividade da transesterificação
(Universidade Federal de São Carlos, 2010-02-26)
The hybrid [CTA+]-SiMCM-41 mesoporous material (where CTA+ is the cetyltrimethylammonium cation) was employed as synthesized in the transesterification reaction between ethyl acetate and methanol. This is a model reaction ...
Desenvolvimento de catalisadores para reforma e oxidação combinadas do metano
(Universidade Federal de São Carlos, 2009-03-20)
In this work, we studied the effects of the promoters of support (ZrO2, La2O3, CeO2, CeO2-ZrO2, CeO2-ZrO2-La2O3 and La2O3) in the nickel catalysts supported on γ-Al2O3 were studied. The supports were prepared by wet ...
Influência do teor metálico na isomerização do n-hexano sobre Ni-Pt/HUSY.
(Universidade Federal de São Carlos, 2003-08-06)
The isomerization of linear alcanes has arised great interest in the industry of refining of oil with the intention to transform n-paraffins (particularly with 6 and 7 carbon atoms), in iso-paraffins, since these last ones ...
Sólidos micro-mesoestruturados tipo zeólita ZSM-5/peneira molecular MCM-41 - síntese e estudo de propriedades.
(Universidade Federal de São Carlos, 2006-08-16)
In the transformation of bulky molecules, the necessity of catalysts that allow the diffusion to and from the active sites located in the interior of the porous system has become of higher interest. The restriction for the ...
Catalisadores à base de Cu, Co ou Fe trocados ou suportados em zeólita USY avaliação na redução de NO com CO
(Universidade Federal de São Carlos, 2008-04-08)
The emissions of the nitrogen oxides (NOx) must be hardly reduced in the next years. The catalytic reduction of NO with CO is one of the possible processes with potential to be able to transform those oxides in N2. In that ...