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Propriedades eletrônicas e estruturais do Cu/ZrO2 aplicadas à reação do etanol
(Universidade Federal de São Carlos, 2012-06-22)
Copper is a typical catalyst for dehydrogenation of ethanol to acetaldehyde. However, copper supported on ZrO2 was found to be extremely active and selective to convert ethanol directly to ethyl acetate. Several reports ...
Estudos sobre a síntese da zeólita Beta na presença de íons fluoreto
(Universidade Federal de São Carlos, 2013-02-27)
One alternative to increase the octane rating of gasoline without the use of toxic or polluting compounds, banned by environmental legislation, is the transformation of linear paraffins of low octane number into branched ...
Zéolitas ZSM-12 mesoporosas textura, cristalinidade e atividade ácida para o craqueamento de cicloexano
(Universidade Federal de São Carlos, 2013-09-12)
The research addressed the generation of mesoporosity in the zeolite ZSM-12 (MTW). In the first part we studied the synthesis of ZSM-12 via conventional methodology and in the presence of a mesopore directing agent, ...
Catalisadores à base de CuO, Fe2O3 ou CuO-Fe2O3 suportados sobre y-Al2O3, ZrO2 ou ZrO2/y-Al2O3 para a redução de NO com CO
(Universidade Federal de São Carlos, 2014-03-31)
NO, NO2 and N2O nitrogen oxides, named NOx, strongly contribute to the air pollution and to minimize their emissions are used catalytic processes. The catalytic reduction of NO with CO has the advantage to simultaneously ...
Reforma a vapor do ácido acético sobre catalisadores de Ni/Al2O3: estudo das rotas reacionais
(Universidade Federal de São Carlos, 2014-02-21)
Acetic acid (AA), one majority substance contained in the bio-oil from biomass pyrolysis, was used as a model molecule for study of reaction routes of steam reforming on Ni/θ-Al2O3 catalysts. The catalyst containing ...
Avaliação do catalisador CTA-MCM-41, modificado por poliacrilatos, na transesterificação de monoéster
(Universidade Federal de São Carlos, 2014-03-24)
The silica hybrid CTA-MCM-41 (where CTA is the cetyltrimethylammonium cation) was synthesized and used in the transesterification of ethyl acetate with methanol. This is a model reaction used to test basic catalysts for ...