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Formação de mesoporosidade em zeólitas ZSM-5: avaliação do método de preparação e do potencial como catalisador ácido através do craqueamento de cicloexano
(Universidade Federal de São Carlos, 2012-04-27)
Due to their potential as acid catalyst and hydrothermal stability, USY, ZSM-5 and modernite zeolites are widely used in several processes of petroleum refining and petrochemical industries. With the discovery of new ...
Síntese e avaliação catalítica das zeólitas com estrutura BEA, MFI e MTW na reação de Knoevenagel
(Universidade Federal de São Carlos, 2014-08-22)
The use of zeolites in basic catalysis is small, especially when compared to the numerous applications of material in their acid form. Inside this context, are even smaller the number of studies on the use of as-synthesized ...
Catalisadores à base de Cu, Zn, Al e Ce aplicados à reação deslocamento gás-água
(Universidade Federal de São Carlos, 2014-03-26)
The water gas-shift reaction (WGS) is an important step in the production process and purification of H2 from hydrocarbon. Commercially, to overcome the thermodynamic and kinetic limitations, this reaction occurs in two ...
Estudo da oxidação preferencial do CO por catalisadores a base de irídio
(Universidade Federal de São Carlos, 2014-03-31)
Ir/Al2O3 samples were prepared to evaluate the influence of the particle size of the metal in the preferential oxidation of CO reaction. Initially, samples with different amounts of iridium were prepared in an attempt to ...
Avaliação do catalisador CTA-MCM-41, modificado por poliacrilatos, na transesterificação de monoéster
(Universidade Federal de São Carlos, 2014-03-24)
The silica hybrid CTA-MCM-41 (where CTA is the cetyltrimethylammonium cation) was synthesized and used in the transesterification of ethyl acetate with methanol. This is a model reaction used to test basic catalysts for ...
Propriedades eletrônicas e estruturais do Cu/ZrO2 aplicadas à reação do etanol
(Universidade Federal de São Carlos, 2012-06-22)
Copper is a typical catalyst for dehydrogenation of ethanol to acetaldehyde. However, copper supported on ZrO2 was found to be extremely active and selective to convert ethanol directly to ethyl acetate. Several reports ...
Efeito do teor de CeO2 em catalisadores de Pt/CeO2-Al2O3 para as reações de oxidação parcial e reforma do metano.
(Universidade Federal de São Carlos, 2005-03-10)
The effect of CeO2 loading in Pt/CeO2-Al2O3 catalysts was investigated. Pt
catalysts supported on mixed CeO2-Al2O3 carriers with different CeO2 loading 1,
3, 6, 12, 20 wt.% were prepared by incipient wetness impregnation ...
Catalisadores de Fe2O3, NiO e Fe2O3 - NiO Suportados in situ em Ce0,5Zr0,5O2 e Ce0,2Zr0,8O2 – Avaliação na Redução de NO com CO
(Universidade Federal de São Carlos, 2014-03-28)
The increasing use of fossil fuels in combustion enginees and power generation plants
has caused a large increase in the emission of sulfur oxides, nitrogen oxides (NOx)
and carbon monoxide into the atmosphere which ...
Catalisadores contendo espécies V2O5 ou VO2+ : atividade e seletividade na redução de NO com amônia
(Universidade Federal de São Carlos, 2009-08-03)
The selective catalytic reduction of NOx with ammonia is the best technology available today to carry out the abatement of nitrogen oxide emissions in industrial gas effluents. Currently, vanadia-titania catalysts promoted ...
Formação de mesoporos na síntese de zeólitas ZSM-5 via nanomoldagem avaliação no craqueamento de n-decano
(Universidade Federal de São Carlos, 2008-04-04)
The use of zeolites in the cracking of hydrocarbons is limited because the molecules higher than 0.74 nm do not diffuse in their micropores. In the other hand, molecular sieves as MCM-41, MCM-48 ou SBA-15, whose diameters ...