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Síntese de hidróxido duplo lamelar: efeitos do processo de secagem
(Universidade Federal de São Carlos, 2020-02-20)
Because of its chemical versatility, ionic exchange and regeneration capacity, Layered Double Hydroxides (LDHs), have recently been recognized as a promising material due to their many application areas. Drying is an ...
Produção de γ-valerolactona a partir de furfural sobre zeólitas Hf/Al-beta – efeito da relação de sítios ácidos de Lewis e Brønsted
(Universidade Federal de São Carlos, 2020-03-19)
Lignocellulosic biomass has been used as a sustainable alternative to organic derivatives of fossil origin for the production of intermediates and chemicals with higher added value. In this context, γ-valerolactone (GVL), ...
Bioadsorção dos inibidores gerados no pré-tratamento da biomassa lignocelulósica em biorrefinarias
(Universidade Federal de São Carlos, 2020-04-29)
In the pretreatment stage of lignocellulosic biomass in biorefineries can release compounds that act as inhibitors of the enzymatic hydrolysis and alcoholic fermentation steps. Among the inhibitors, the phenolic compounds ...
Estudo sobre o desempenho de válvulas não-mecânicas como alimentadores de biomassa residual de borra de café em reatores de leito pneumático circulante: experimentação e modelagem via CFD-TFM
(Universidade Federal de São Carlos, 2020-08-24)
The continuous and stable feeding of particulate solids to reactors is essential for energy cogeneration in industrial processes, for example, by using biomass residues. Nevertheless, flow instabilities and blockage of ...
Avaliação técnica da gaseificação do bagaço de cana-de-açúcar em reator contínuo de leito fluidizado
(Universidade Federal de São Carlos, 2020-02-19)
The sugar and alcohol sector introduces a big potential to expand the production lines of ethanol, sugar and clean electric energy with a profitable harnessing of its residues and sub products, like sugar cane bagasse. The ...
Esterificação de glicerol com ácido benzoico sobre zeólitas H-ZSM-5 hierárquicas incorporadas com Zr ou Nb
(Universidade Federal de São Carlos, 2020-03-19)
Acid zeolites are microporous aluminosilicates, which exhibit negative charged AlO4- tetrahedrons in its lattice balanced by protons (H+), generating Brønsted acid sites (BAS). The Lewis acidity of zeolites is commonly ...
Compreendendo a reação ‘step-wise’ de conversão de metano a metanol usando zeólitas trocadas ionicamente com cobre
(Universidade Federal de São Carlos, 2020-03-06)
Methane (CH4) is a stable molecule abundantly found on our planet with reserves even
greater than crude oil. Due to its high availability and environmental impacts caused by
its emission into the atmosphere, the development ...
Immobilization of enzymes of agroindustrial interest on hydroxyapatite nanoparticles: β-glucosidase, xylase and phytase
(Universidade Federal de São Carlos, 2020-03-10)
Industrial processes are increasingly requiring environmentally sustainable technologies and the use of enzymes is relevant due to the selectivity and specificity of these biocatalysts. However, the application of soluble ...
Modelagem e análise experimental do escoamento de esferas macias em fluidos viscosos: estudo de colisões partícula-partícula e partícula-superfície e da interação partícula-fluído
(Universidade Federal de São Carlos, 2020-02-20)
Solid-fluid flows are widely used in chemical, biochemical, food and petroleum processes. These include crystallization and sedimentation steps, hydrometallurgical operations, backwashing of granular filters, adsorption ...
Determinação experimental de parâmetros de interação e aplicação na simulação CFD-DEM de leito de jorro
(Universidade Federal de São Carlos, 2020-02-19)
Spouted beds feature the intense mixture of solids, which favors the mechanisms of heat and mass transfer. The understanding of these phenomena is associated with the difficult to obtain details of fluid dynamics by the ...