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Síntese e propriedades de sílicas híbridas contendo surfactantes catiônicos
(Universidade Federal de São Carlos, 2015-09-21)
The control of pore geometry and pore diameter of silica mesoporous materials is
necessary for application of these materials, mainly in industrial process that depends on the shape selectivity. This way, considerable ...
Estudo de catalisadores de cobre suportados para a reação de oxidação preferencial do CO
(Universidade Federal de São Carlos, 2010-06-30)
The CO preferential oxidation reaction (PROX-CO) has been widely studied in last few years. Aiming H2 purification for proton-exchange membrane cells (PEMFC) use, the main role of the PROX-CO reaction should be reduce the ...
Influência do método de preparação de catalisadores bifuncionais, Pt-Ni/HUSY, na isomerização do n-hexano
(Universidade Federal de São Carlos, 2008-02-25)
Gasoline containing high amount of linear chain compounds have low
octane number. However, this number can be increased when linear alkanes are
subjected to isomerization, able to change linear chain compounds to ...
Isomerização do n-heptano sobre catalisadores bifuncionais Pt-Ni suportados em zeólitas BEA e FAU
(Universidade Federal de São Carlos, 2009-12-09)
The objective of this paper was to study the influence of metal loading content on the properties of bimetallic catalysts, formed by Pt and Ni, supported on zeolite HUSY and HBEA. Another objective of this study was to ...
Nanopartículas de Pt suportadas em Al2O3 e CeO2-Al2O3: síntese e caracterização de catalisadores aplicados à reação de deslocamento gás-água
(Universidade Federal de São Carlos, 2011-04-28)
Colloidal Pt nanoparticles were synthesized according to an adapted procedure from Song and co-workers [1], which it was based on the reduction of dihydrogen hexachloroplatinate by ethylene glycol in a basic solution, but ...
Preparação e aplicação de óxidos tipo perovskita La1-xCexNiO3 e La1-xCaxNiO3 para obtenção de gás de síntese a partir do metano.
(Universidade Federal de São Carlos, 2006-04-20)
Catalysts precursors with perovskite structure like La1-xCexNiO3 ( x = 0,
0.03, 0.05, 0.1, 0.4 ,0.7) and La1-xCaxNiO3 (x = 0, 0.05, 0.1, 0.3, 0.5, 0.8) have
been prepared by three different methods: precipitation, citrate ...
Catalisadores de Pt suportados, obtidos pelo método solgel : efeito do cério na atividade e estabilidade nas reações de reforma do metano
(Universidade Federal de São Carlos, 2009-12-11)
The effect of Ce as a structural and electronic promoter on the activity and stability of Pt catalysts supported on Al2O3 for methane reforming reactions were investigated to elucidate the metal-support interaction. Pt/Al2O3 ...
Estudo da preparação e das propriedades estruturais de catalisadores para a transformação do metano em gás de síntese e hidrocarbonetos
(Universidade Federal de São Carlos, 2010-06-15)
Pt catalysts supported on CeO2-La2O3-Al2O3, with different mixed oxide compositions, and CeO2-ZrO2-Al2O3, prepared using three different routes, were synthesized by sol gel technique. The samples were characterized using ...
Síntese e avaliação de sílica tipo M41S contendo cátions CTA em transesterificação catalítica
(Universidade Federal de São Carlos, 2010-08-13)
The investments in the biofuel production have increased a lot in the last years mainly because of smaller damages they cause to the environment in comparison with the derived conventional petroleum fuels. The reaction of ...
Desenvolvimento de catalisadores para reforma e oxidação combinadas do metano
(Universidade Federal de São Carlos, 2009-03-20)
In this work, we studied the effects of the promoters of support (ZrO2, La2O3, CeO2, CeO2-ZrO2, CeO2-ZrO2-La2O3 and La2O3) in the nickel catalysts supported on γ-Al2O3 were studied. The supports were prepared by wet ...