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Estudo da influência de baixos teores de platina em catalisadores Ni/γ-Al2O3 nos processos de reforma a vapor, oxidação parcial e reforma oxidativa do metano.
(Universidade Federal de São Carlos, 2002-08-22)
The effect of platinum addition in low contents (0.1 and 0.3 % wt.) in nickel supported γ−alumina catalyst (15% Ni wt.) has been investigated. The samples were prepared by successive wet impregnations of metal ions over ...
Nanopartículas de Co suportadas em SiO2: síntese, caracterização e propriedades catalíticas para a reforma a vapor do etanol
(Universidade Federal de São Carlos, 2007-03-16)
Colloidal Co Nanoparticles (Co-NPs) were used to prepare supported Co catalysts. The Co-
NPs were obtained by thermal decomposition of the precursor Co2(CO)8 in the presence of
oleic acid and trioctylphosphine oxide ...
Desenvolvimento de catalisadores para reforma e oxidação combinadas do metano
(Universidade Federal de São Carlos, 2009-03-20)
In this work, we studied the effects of the promoters of support (ZrO2, La2O3, CeO2, CeO2-ZrO2, CeO2-ZrO2-La2O3 and La2O3) in the nickel catalysts supported on γ-Al2O3 were studied. The supports were prepared by wet ...
Influência do teor metálico na isomerização do n-hexano sobre Ni-Pt/HUSY.
(Universidade Federal de São Carlos, 2003-08-06)
The isomerization of linear alcanes has arised great interest in the industry of refining of oil with the intention to transform n-paraffins (particularly with 6 and 7 carbon atoms), in iso-paraffins, since these last ones ...
Sólidos micro-mesoestruturados tipo zeólita ZSM-5/peneira molecular MCM-41 - síntese e estudo de propriedades.
(Universidade Federal de São Carlos, 2006-08-16)
In the transformation of bulky molecules, the necessity of catalysts that allow the diffusion to and from the active sites located in the interior of the porous system has become of higher interest. The restriction for the ...
Catalisadores à base de Cu, Co ou Fe trocados ou suportados em zeólita USY avaliação na redução de NO com CO
(Universidade Federal de São Carlos, 2008-04-08)
The emissions of the nitrogen oxides (NOx) must be hardly reduced in the next years. The catalytic reduction of NO with CO is one of the possible processes with potential to be able to transform those oxides in N2. In that ...
Influência do método de preparação e performance catalítica para os catalisadores de Pd-La2O3-Al2O3 aplicados na reforma autotérmica do metano
(Universidade Federal de São Carlos, 2008-05-21)
Pd catalysts supported on Al2O3 and La2O3-Al2O3 (12 wt.% La2O3) were
prepared by wetness impregnation method with aqueous solution of of palladium nitrate
(1 wt.% Pd). The supports were obtained by conventional method ...
Formação de mesoporos na síntese de zeólitas ZSM-5 via nanomoldagem avaliação no craqueamento de n-decano
(Universidade Federal de São Carlos, 2008-04-04)
The use of zeolites in the cracking of hydrocarbons is limited because the molecules higher than 0.74 nm do not diffuse in their micropores. In the other hand, molecular sieves as MCM-41, MCM-48 ou SBA-15, whose diameters ...
Reforma a vapor do etanol sobre catalisadores de Ni e Co suportados
(Universidade Federal de São Carlos, 2004-08-17)
The Ni and Co catalysts supported on Al2O3 and 12%La-Al2O3 and the carrier 12%La-Al2O3 were prepared by impregnation of the support with an aqueous solution of corresponding nitrates metals. The catalysts were characterized ...