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Estudo espectroscópico por FTIR da conversão de etanol em catalisadores de Au suportados
(Universidade Federal de São Carlos, 2020-07-25)
In this work, an FTIR spectroscopic study of gold catalysts supported on monoclinic zirconia (with Au content of 2,5% w/w), was carried out in order to elucidate the surface nature of this catalyst in the dehydrogenation ...
Avaliação in vitro da ação fotodinâmica antimicrobiana e antitumoral do complexo cis-[Ru(phen)2(pPDIp)]2+
(Universidade Federal de São Carlos, 2021-02-19)
Photodynamic therapy (PDT) activates a photosensitizer by visible or infrared light to generate cytotoxic oxygen species that lead to cell death. PDT is generally used in applications in superficial lesions and can be used ...
Imagens espectrais do processo de agregação da insulina por complexos metálicos luminescentes
(Universidade Federal de São Carlos, 2021-03-01)
Insulin is a protein hormone synthesized by β cells in the pancreas, which regulates the level of glucose in the blood. This protein was the first biopharmaceutical produced on an industrial scale for the treatment of ...
Síntese de complexos de Mg(II), atividade antioxidante e citotóxica
(Universidade Federal de São Carlos, 2021-03-09)
The objective of this work was to develop metal complexes containing natural products that have antioxidant activity to be applied in the cosmetics sector. For that, 3 [Mg(phen)2PN]+ metal complexes were synthesized and ...
Evaluation of the biological activity of the disintegrin-like and cysteine-rich domains of Bothropasin, a metalloproteinase from Bothrops jararaca
(Universidade Federal de São Carlos, 2021-05-17)
Bothropasin is a 48kDa hemorrhagic class III Snake Venom Metalloproteinase (SVMP). As a multi-domain protein, it contains catalytic metalloproteinase (M), disintegrin-like (D), and cysteine rich domains (C). Integrins ...
Determinação de Si e Y em amostras agronômicas por espectrometria de emissão óptica com plasma induzido por micro-ondas
(Universidade Federal de São Carlos, 2021-05-20)
Different demands for analytical responses are presented in agricultural research. In this approach, this dissertation, divided into two chapters, seeks to offer analytical alternatives for plant breeding and fish nutrition ...
Eletrodo de pasta de carbono modificado com solvente eutético profundo hidrofóbico e sua aplicação voltamétrica
(Universidade Federal de São Carlos, 2021-03-01)
In this work, the use of hydrophobic deep eutectic solvent was proposed for the modification of carbon paste electrodes. Different HDES were prepared using fatty acids: octanoic, decanoic, and dodecanoic acids, and ...
Desenvolvimento de eletrodo modificado com o solvente eutético profundo cloreto de colina/glicerol para a determinação simultânea de paracetamol e diclofenaco
(Universidade Federal de São Carlos, 2021-04-22)
In this master’s dissertation has investigated the use of deep eutectic solvents (DES) for the development of electrochemical sensors. DES was immobilized on the surface of a glassy carbon electrode (GCE) within carbon ...
Perfil químico e dinâmica espacial e temporal de flavonoides de soja [Glycine Max (L.) Merr.].
(Universidade Federal de São Carlos, 2021-03-11)
The soybean (Glycine max) is a legume species originally from China, belonging to the Fabaceae family. This crop is exposed throughout its cycle to attack by different species of insect pests, which can affect the plant ...
As propriedades espectroscópicas, fotoquímicas, fotofísicas e eletroquímicas do complexo de Ru(II) cis-[Ru(tbbpy)2(4Apy)2]2+, em que tbbpy = 4,4’-ditert-butil-2,2’-bipiridina e 4Apy = 4-Aminopiridina
(Universidade Federal de São Carlos, 2021-04-28)
This work involves the synthesis and characterization of the cis-[Ru(tbbpy)2(4Apy)2]2+ complex where tbbpy = 4,4'-di-tert-butyl-2,2'-bipyridine and 4Apy = 4-Aminopyridine, determination of spectroscopic, photochemical and ...