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Obtenção de sulfetos metálicos (M= Ni, Mo) pelo método solvotermal assistido por micro-ondas aplicados na reação de desprendimento de hidrogênio
(Universidade Federal de São Carlos, 2020-03-27)
In general, transition metal sulfides show good activity in the Hydrogen Evolution Reaction (HER). Some of these metals, such as Mo and Ni, arouse interest in the area of electrocatalysis, since they are more abundant and ...
Síntese de miméticos da urease de Canavalia ensiformis e avaliação mecanística da decomposição da ureia
(Universidade Federal de São Carlos, 2020-02-20)
Urease is a metalloenzyme found in many different organisms, which is also associated to virulence factors, such as pielonefritis. Hence, the study of urease inhibitors is necessary to control its activity. For a better ...
Desenvolvimento de dispositivo microfluídico descartável contendo arranjos de biossensores para a determinação multiplexada de espécies de interesse biológico em diferentes matrizes
(Universidade Federal de São Carlos, 2020-10-30)
16 sensing points for the construction of an array of biosensors. The components of this device have been individually evaluated and their construction design has been optimized for the best performance of the sensors. ...
Flow chemistry applied to hazardous reactions, and fluorophores synthesis with photophysics studies
(Universidade Federal de São Carlos, 2020-02-20)
Two distinct cases of continuous flow conditions applied to dangerous reactions are described. The first example is the continuous photooxygenation of a series of dienes that produces endoperoxides and / which are potentially ...
Caracterização das interações químicas entre os microrganismos simbiontes das formigas cortadeiras
(Universidade Federal de São Carlos, 2021-01-13)
The complex symbiosis in Attini ant nests inspires curiosity in different fields of research from Microbiology to Chemical Ecology. These ants cultivate their mutualist fungus for approximately 50 million years in structures ...
Co-cultivo fúngico como estratégia para obtenção de metabólitos biologicamente ativos
(Universidade Federal de São Carlos, 2021-02-23)
In this work, the bactericidal, antiprotozoal, and inhibition of cathepsin V proteolytic activity of extracts from the axenic cultivation of six fungal species (Fusarium guttiforme, Pestalotiopsis diospyri, Phoma ...
Síntese, caracterização e avaliação da atividade fotoeletrocatalítica de filmes finos de Sb2S3
(Universidade Federal de São Carlos, 2020-08-27)
Photoelectrochemical cells (PECs) have been shown to be a promising system for H2 generation from photoelectrolysis of water. Among the semiconductors materials that have been studied for PECs, Sb2S3 stands out due to its ...
Avaliação da atividade citotóxica de complexos fosfínicos de Ru(II) com ligantes mercaptos e aciltioureias
(Universidade Federal de São Carlos, 2020-12-11)
In this thesis, two series of new Ru-phosphine complexes containing mercapto or acylthiourea ligands were synthesized, characterized and assessed their cytotoxic activities. The first series is composed of five complexes ...
Efeito da inserção de nanopartículas de TiO2-OPM sobre as propriedades do PET reciclado
(Universidade Federal de São Carlos, 2021-04-26)
Poly (ethylene terephthalate) (PET) is one of the most consumed polymers today, mainly in the fast-disposable beverage market, its excellent properties associated with its low production cost, make it one of the most ...
UVC-based advanced oxidation processes for water treatment: laboratory and pilot plant scale studies
(Universidade Federal de São Carlos, 2020-09-21)
The challenge of providing good-quality water free from contaminants of emerging concern (including organic microcontaminants; OMCs) and pathogens is one of the main hot topics worldwide. Thus, the efficiency of different ...