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Sustainable synthesis of ciclopentene derivatives through multicomponent reactions in continuous flow regime
(Universidade Federal de São Carlos, 2020-03-25)
Sustainable chemistry has gained relevance in recent years, not only in the fine chemical industry, but also in organic synthesis. This new conception of chemistry allows the development of environmentally friendly processes, ...
A reação de Diels-Alder de p-Benzoquinonas em versão multicomponente
(Universidade Federal de São Carlos, 2005-08-24)
A study of the multicomponent version of the Diels-Alder reaction of para-benzoquinones has been proposed, with the idea of uniting the versatility of the reaction with the simplicity of the methodology. The key step ...
Organocatálise assimétrica e sistemas vinílogos: adição de 1,3-oxazolina-2-tionas a aldeídos a,b-insaturados
(Universidade Federal de São Carlos, 2017-03-16)
The use of organic molecules in stereoselective transformations has emerged as a powerful tool for the efficient construction of chiral skeletons and complementing existing methods. Currently, a great variety of reactions ...
Parametrização de ligantes em Co(salen) aplicados na despolimerização de ligninas
(Universidade Federal de São Carlos, 2022-05-26)
Since the industrial revolution, fossil sources such as oil, natural gas or coal have become indispensable resources for human development with a variety of uses: from energy generation to drugs production and household ...
Reações de fotooxigenação de pinenos em pinocarvonas, trans-pinocarveóis e mirtenal: uma abordagem em regime de fluxo contínuo
(Universidade Federal de São Carlos, 2022-04-18)
In this work, a continuous flow protocol to prepare (-)-pinocarvone, (-)-trans-
pinocarveol and (+)-myrtenal from (+)--pinene, (-)--pinene and -pinene through
photooxygenation reactions was described. Furthermore, ...
Arilsulfonilação tri componente de diidrofurano e ésteres vinílicos via catálise dual níquel/fotorredox
(Universidade Federal de São Carlos, 2022-03-29)
The pursuit of synthetic protocols aligned to sustainability goals, increasingly necessary in the global context in which we operate, caused a great effort by synthetic chemists to develop photocatalytic methodologies ...
Síntese de uma coleção de cumarinas, possíveis inibidores da enzima acetilcolinesterase
(Universidade Federal de São Carlos, 2010-08-13)
Alzheimer's disease is associated with decreased rates of acetylcholine (ACh) in synaptic process, decreasing the cortical cholinergic transmission, and other neurotransmitters such as norepinephrine, dopamine, serotonin, ...
Síntese de furanos trissubstituídos via reações de oxopaladação aeróbica
(Universidade Federal de São Carlos, 2019-02-25)
Furans are important heterocyclics with broad application in synthesis as a building block, frequently presented in a wide range of compounds that exhibit biological activity, including natural products. Intramolecular ...
Síntese assimétrica dos componentes do feromônio sexual da lagarta-parda, Thyrinteina arnobia (Lepidoptera: Geometridae)
(Universidade Federal de São Carlos, 2013-01-31)
The pheromones play an important role in chemical communication between alive organisms. They can be used in agriculture to pest control. The brown-caterpillar, Thyrinteina arnobia, is considered in Brazil a major pest of ...