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Otimização e validação de metodologias analíticas em GC-MS aplicadas à biodegradação de poluentes orgânicos persistentes e óleo essencial de pimentas
(Universidade Federal de São Carlos, 2019-02-26)
Recently, a large number of compounds have been synthesized in order to bring comfort and convenience to everyday life. These products, however, produce a large amount of daily waste that are released into the environment ...
Estudo do potencial eletrostático e da termodinâmica de agregação de surfactantes por simulações de dinâmica molecular
(Universidade Federal de São Carlos, 2018-03-13)
Due to the amphiphilic character, the surfactants tend to be adsorbed at the water surface and, in concentrations larger than the critical micellar concentration, they self-assembling in solution with the purpose to reduce ...
Investigação das propriedades ópticas e fotocatalíticas de materiais a base de fosfato de prata
(Universidade Federal de São Carlos, 2019-08-05)
The semiconductor-based photocatalytic degradation of synthetic dyes has been considered a promising approach in wastewater treatment. The main objective in this doctoral thesis was the investigation on structural, ...
Estratégias espectroanalíticas para análise química inorgânica de plantas medicinais
(Universidade Federal de São Carlos, 2014-12-01)
This thesis describes the development of analytical procedures based on direct solid analysis by high-resolution continuum source atomic absorption spectrometry in graphite furnace (SS-HR-CS GF AAS) and aqueous solutions ...
Estudo químico do fungo Colletotrichum acutatum e sua interação com Citrus sinensis
(Universidade Federal de São Carlos, 2014-11-06)
Brazil remains the world's largest orange producer, accounting for 32% of the total production of oranges and 50% orange juice. The State of São Paulo holds 97% of Brazilian exports of orange juice, possessing one of the ...
Complexos de rutênio(II) com potenciais atividades antitumorais: síntese, caracterização e ensaios biológicos
(Universidade Federal de São Carlos, 2013-12-13)
In this thesis phosphinic ruthenium complexes coordinated to ligands of biological interest: folic acid, 6-mercaptopurine, 2-mercaptopyridine and 8-aminoquinoline, dpqQX, dppz and dpq (dipyridophenazine and derivatives) ...
Especiação química de As e Cd por HPLC-ICP-MS em forrageira Brachiaria brizantha Stapf. cv. Marandu cultivada em solo previamente contaminado
(Universidade Federal de São Carlos, 2014-03-21)
Recent research and advances in analytical chemistry show that the total content determination of an element, although it is essential, is limited since it is not sufficient to provide information about the bioavailability ...
Desenvolvimento de materiais mesoporosos baseados em sílica oriunda de biomassa para utilização como sistema remediador de hidrocarbonetos policíclicos aromáticos
(Universidade Federal de São Carlos, 2017-08-04)
This work describes the synthesis and characterization of mesoporous materials from the use of amorphous silica extracted from rice husk ashes (RHAs), as well as the preparation of mixed matrix membranes (MMMs) using the ...
Desenvolvimento de imunossensores piezelétrico e eletroquímico para detecção de amostras de interesse agronômico e de saúde
(Universidade Federal de São Carlos, 2012-07-23)
This work shows development of immunosensors for agronomic interest and public heath. The first was a piezoeletric immunosensor to detect a cysteine peptidase, a potencial biomarker for Xanthomonas citri subsp. citri that ...
Efeito da inserção de nanopartículas sintéticas preparadas por rota coloidal em matriz acrílica comercial de uso odontológico
(Universidade Federal de São Carlos, 2016-03-11)
Acrylic resins are very used in dentistry to dental restorations and manufacture of
prostheses. New compositions of acrylic resin have been developed through the
incorporation of silver nanoparticles due to the antimicrobial ...