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Complexos fosfínicos de Ru(II)/mercaptos contendo ligantes N,N-heterocíclicos: atividade citotóxica e mecanismo de ação
(Universidade Federal de São Carlos, 2022-12-16)
The main objectives of this study were the synthesis, characterization and biological studies of two series of ruthenium phosphine compounds containing different mercapto ligands, and contrasting in N,N-heterocyclic ligands ...
Desenvolvimento de um dispositivo eletroquimiluminescente de baixo custo para detecção do SARS-CoV-2 em saliva
(Universidade Federal de São Carlos, 2023-03-09)
This work is a response to the COVID-19 pandemic, in which a new method for detecting the SARS-CoV-2 virus in saliva based on genome-genetic assay performed at room temperature is proposed. The method allows the detection ...
Estudo metabolômico de espécies de Picramnia e reavaliação da classificação morfológica do gênero
(Universidade Federal de São Carlos, 2023-04-28)
The species Picramnia sellowii Planch. is a species of the order Picramniales, in the family Picramniaceae, with the vernacular name “Gogoia”. In reviews of the genus Picramnia and according to the APG IV reclassification, ...
Photocatalytic controlled oxidation reaction of methane
(Universidade Federal de São Carlos, 2023-06-28)
The CH4 partial oxidation into value-added chemicals by solar means has been discussed as alternative for emission abatement, a fundamental topic for sustainable production with lower global warming gas emissions in future. ...
Eletrodeposição de filmes do tipo Ni-X (X=P, Cu ou Cu-P) a partir de banhos contendo aspartato
(Universidade Federal de São Carlos, 2022-11-25)
In the present work, aspects related to the electrodeposition of Ni-based metal films - either pure metal or Ni-P, Ni-Cu, and Ni-Cu-P alloys - from baths containing aspartate complexes as electroactive species and hypophosphite ...
In situ chemical oxidation of ciprofloxacin by activated peroxymonosulfate using nanometric MnOOH: investigation of operational parameters and changes on the catalyst surface
(Universidade Federal de São Carlos, 2023-05-24)
Nanometric MnOOH compound was synthesized by a green approach, characterized, and used to remove ciprofloxacin (CIP) antibiotic by in situ chemical oxidation using peroxymonosulfate (PMS). The effects of varying concentrations ...
Correlação estrutura x propriedades de transporte de CO2 em membranas de poli(éterimida)/líquido iônico
(Universidade Federal de São Carlos, 2017-09-28)
The increase in the emission of carbon dioxide (CO2) from the burning of fossil fuels contributes directly to changes in the environment. For post-combustion CO2 capture, the use of polymer membranes has gained prominence ...
Nanocompósitos na forma de fibras poliméricas à base de policaprolactona com hidrotalcita imobilizada para a adsorção de ácido clorogênico
(Universidade Federal de São Carlos, 2023-08-25)
Water, vital for humanity, is widely used in coffee processing, resulting in effluents with a high organic load, including polyphenols that can be harmful to the environment. Adsorption is a simple and effective strategy ...
Material particulado atmosférico de São Carlos: identificação das fontes de emissões e seus impactos à saúde humana
(Universidade Federal de São Carlos, 2023-08-30)
Air pollution by particulate matter (PM) is one of the main environmental risks to human health. PM has different sizes, emission sources, and a wide range of substances may be present in it. Given this scenario, the ...
Citotoxidade e mecanismo de ação de complexos Ru(II)/2-mercapto-4(3H)quinazolinona em células de câncer de pele
(Universidade Federal de São Carlos, 2023-02-28)
Ruthenium biphosphynic complexes combined with mercapto ligands have shown low IC50 values and good selectivity indexes (SI) in different tumor lines studied, which has motivated the development of ruthenium compounds with ...