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Reforma a vapor de acetona sobre catalisadores de Ni e Co/MgAl2O4: efeito das propriedades redox dos reagentes e dos catalisadores nos caminhos de reação
(Universidade Federal de São Carlos, 2014-12-12)
The Steam reforming of Acetone (SRA) reaction was studied on magnesium aluminate (MgAl2O4) supported nickel (Ni) and cobalt (Co) catalysts. The catalysts with 8 wt.% of Ni, Co or Ni-Co were prepared by dry impregnation and ...
Síntese de acil fosfodiésteres por mecanoquímica: uma metodologia de química verde
(Universidade Federal de São Carlos, 2019-08-22)
Green chemistry is very concerned with the sustainability of chemical reactions, where one of the objectives, which in the formulation/remodeling of synthetic routes can replace toxic solvents with solvents of lower toxicity, ...
Fosfoenolpiruvato carboxiquinase imobilizada: novos modelos de triagem de ligantes
(Universidade Federal de São Carlos, 2019-08-30)
Phosphoenolpyruvate carboxykinase (PEPCK) is a ubiquitous enzyme found in all known groups of organisms, acting in the reversible conversion of oxaloacetate (OAA) to phosphoenolpyruvate (PEP) and CO2, in the presence of ...
Estudos bioquímicos e cinéticos de acetilcolinesterases de formigas cortadeiras (Atta sexdens)
(Universidade Federal de São Carlos, 2017-09-29)
Acetylcholinesterase (AChE) (EC 3.1.1.7) is the enzyme responsible for catalyzing the hydrolysis of the neurotransmitter acetylcholine leading to the release of acetate and choline. In insects, acetylcholine is one of the ...
Identificação assistida por docking molecular de potenciais alvos em Plasmodium falciparum para derivados de indol-3-glioxiltirosina com atividade antimalárica in vitro
(Universidade Federal de São Carlos, 2020-07-28)
Malaria, although it is no longer considered a neglected disease, remains a public health problem. In 2018 alone, the World Health Organization estimated 228 million new cases and 405,000 deaths worldwide. Currently, ...
Reações fotoquímicas promovidas por luz visível para a síntese de compostos heterocíclicos
(Universidade Federal de São Carlos, 2017-07-27)
In the last decades, the emphasis and application of the principles of Green Chemistry have inspired a change of behavior, both in industry and academy, towards a more sustainable chemistry aiming the synthesis of the ...
Electrochemistry and STM-assisted Molecular electronics study of bimetallic hexaphyrins
(Universidade Federal de São Carlos, 2019-09-23)
ELECTROCHEMISTRY AND STM-ASSISTED MOLECULAR ELECTRONICS STUDY OF BIMETALLIC HEXAPHYRINS. The electron transport in porphyrinoids are related to several bioprocesses in Nature, from conversion from solar energy to chemical ...
Obtenção de derivados de compostos isolados de Zingiber officinale por biotransformação e semi-síntese e avaliação frente à cisteinil-proteases
(Universidade Federal de São Carlos, 2016-07-01)
Several aromatic polyketide derivatives from Ginger (Zingiber officinale), like zingerone,
6-gingerol and 6-shogaol were obtained by biocatalytic reactions and semi-synthesis and
both their antifungal and cysteine-proteinase ...
Estudos teóricos e experimentais de complexos de cobre: propriedades espectroscópicas e atividade biológica
(Universidade Federal de São Carlos, 2020-07-28)
Cancer is the second leading cause of death in the world. The scientific community is mobilizing to study new compounds with cytotoxic potential and that can be used as molecular probes. However It is important to highlight ...
Sachês compósitos biodegradáveis à base de amido visando o acondicionamento de nutrientes para aplicação como fertilizantes
(Universidade Federal de São Carlos, 2020-07-31)
The Brazilian agrarian system is responsible for a large part of the national GDP, even though agricultural production is dependent on foreign trade. In addition, many producers prioritize the use of NPK-type fertilizers ...