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Compostos de metais de transição neuroativos: investigações fotoquímicas, fotofísicas, físico-químicas e citotoxicidade para drogas neuroativas em fase III
(Universidade Federal de São Carlos, 2010-10-29)
The photochemical and photophysical properties of the cis-[Ru(α-diimine)2(4Apy)2]2+ complexes where 4Apy= 4-aminopyridine, α-diimine = 1,10 -phenanthroline (phen) (1), 4,7 -diphenyl-1,10 -phenanthroline (Ph2phen) ...
Estudo sobre o mecanismo de reações de hidrogenação em complexos do tipo [RuCl2(P)2(N)2][(P)2= mono ou bifosfina; N= piridina ou derivados]
(Universidade Federal de São Carlos, 2010-03-26)
In this study, it was performed synthesis and characterization of the complexes of general formula cis-[RuCl2(PPh3)2(N)2], cis-[RuCl2(PPh3)2(N-N)], trans- [RuCl2(dppb)(N)2], cis-[RuCl2(dppb)(N-N)] and cis-[RuCl2(P-P)(N-N)] ...
Complexos de Ru (II) com ligantes de interesse biológico: síntese, caracterização e citotoxicidade
(Universidade Federal de São Carlos, 2011-02-04)
Three new Ru(II) complexes where were synthesized and characterized. The formulas were [RuCl(dmpm)2NO], [Ru(dmpm)2(dppb)] and [Ru(pic)2(dppb)], where dmpm = 4,6-dimethyl-2-mercaptopyrimidine, dppb = 1,4- bis(diphenylphos ...
Complexos de Ru e Pd com bases de Schiff de ditiocarbazatos com interesse bioinorgânico e quimioterápico
(Universidade Federal de São Carlos, 2010-04-16)
The present work reports the synthesis of dithiocarbazate Schiff s bases, which are versatile ligands with a significant interest due to both property and biological application. The focus of this study was the synthesis ...
Complexos fosfínicos de rutênio contendo os ligantes nitro, nitrosilo ou piridinas, com atividades antitumorais e antituberculose
(Universidade Federal de São Carlos, 2010-11-10)
In this work, a series of cis-[RuCl(L)(dppb)(5-mebipy)]PF6 (L=pyridine, 4- metylpyridine, 4-phenylpyridine, 4-vinylpyridine, 4-terc-butylpyridine and 4- aminopyridine); the cis-[RuCl(NO2)(dppb)(5-mebipy)], the cis-[Ru(NO ...