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Catalisadores à base de Cu, Zn, Al e Ce aplicados à reação deslocamento gás-água
(Universidade Federal de São Carlos, 2014-03-26)
The water gas-shift reaction (WGS) is an important step in the production process and purification of H2 from hydrocarbon. Commercially, to overcome the thermodynamic and kinetic limitations, this reaction occurs in two ...
Estudo da oxidação preferencial do CO por catalisadores a base de irídio
(Universidade Federal de São Carlos, 2014-03-31)
Ir/Al2O3 samples were prepared to evaluate the influence of the particle size of the metal in the preferential oxidation of CO reaction. Initially, samples with different amounts of iridium were prepared in an attempt to ...
Avaliação do catalisador CTA-MCM-41, modificado por poliacrilatos, na transesterificação de monoéster
(Universidade Federal de São Carlos, 2014-03-24)
The silica hybrid CTA-MCM-41 (where CTA is the cetyltrimethylammonium cation) was synthesized and used in the transesterification of ethyl acetate with methanol. This is a model reaction used to test basic catalysts for ...
Propriedades eletrônicas e estruturais do Cu/ZrO2 aplicadas à reação do etanol
(Universidade Federal de São Carlos, 2012-06-22)
Copper is a typical catalyst for dehydrogenation of ethanol to acetaldehyde. However, copper supported on ZrO2 was found to be extremely active and selective to convert ethanol directly to ethyl acetate. Several reports ...
Efeito do teor de CeO2 em catalisadores de Pt/CeO2-Al2O3 para as reações de oxidação parcial e reforma do metano.
(Universidade Federal de São Carlos, 2005-03-10)
The effect of CeO2 loading in Pt/CeO2-Al2O3 catalysts was investigated. Pt
catalysts supported on mixed CeO2-Al2O3 carriers with different CeO2 loading 1,
3, 6, 12, 20 wt.% were prepared by incipient wetness impregnation ...
Catalisadores contendo espécies V2O5 ou VO2+ : atividade e seletividade na redução de NO com amônia
(Universidade Federal de São Carlos, 2009-08-03)
The selective catalytic reduction of NOx with ammonia is the best technology available today to carry out the abatement of nitrogen oxide emissions in industrial gas effluents. Currently, vanadia-titania catalysts promoted ...
Formação de mesoporos na síntese de zeólitas ZSM-5 via nanomoldagem avaliação no craqueamento de n-decano
(Universidade Federal de São Carlos, 2008-04-04)
The use of zeolites in the cracking of hydrocarbons is limited because the molecules higher than 0.74 nm do not diffuse in their micropores. In the other hand, molecular sieves as MCM-41, MCM-48 ou SBA-15, whose diameters ...
Oxidação preferencial de CO em catalisadores à base de ouro : estudo do efeito do suporte e do método de síntese do catalisador
(Universidade Federal de São Carlos, 2016-03-29)
The CO preferential oxidation reaction (PROX) is used in the purification of hydrogen
streams for various applications. Since the discovery of improved catalytic properties
of gold particles, at nanometer range, in the ...
Aproveitamento de CO2 para a produção de metanol e compostos C2+ aplicando catalisadores à base de Cu e Fe
(Universidade Federal de São Carlos, 2021-08-10)
Considering the approaches to use of the CO2, this work aimed to study CO2 hydrogenation at gas phase and CO2 reduction (CO2RR) via electrocatalysis. Through these methodologies a wide variety of value-added products can ...
Reforma a vapor do etanol sobre catalisadores de Ni e Co suportados
(Universidade Federal de São Carlos, 2004-08-17)
The Ni and Co catalysts supported on Al2O3 and 12%La-Al2O3 and the carrier 12%La-Al2O3 were prepared by impregnation of the support with an aqueous solution of corresponding nitrates metals. The catalysts were characterized ...