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Desenvolvimento de catalisadores bifuncionais a base de fosfato e suas aplicações catalíticas
(Universidade Federal de São Carlos, 2022-02-17)
The development of bifunctional acid catalysts is an area of heterogeneous catalysis in intense growth, mainly due to the possibility of performing consecutive reactions using a single catalyst and a single reactor. In ...
Modificação de semicondutores de Sb2Se3 com co-catalisadores de MoSx e Pt para a produção de hidrogênio verde via water splitting solar
(Universidade Federal de São Carlos, 2022-11-23)
Sb2Se3 semiconductors have been shown to be excellent photocathodes with attractive optoelectronic properties when compared to other photoabsorbers commonly used. However, its photocorrosion in aqueous media prevents it ...
Precious, strategic and toxic elements in electronic waste: bibliometric evaluation, proposition of reference material and direct analysis by laser-based techniques and fluorescence spectrometry
(Universidade Federal de São Carlos, 2021-03-26)
Waste electrical and electronic equipment (WEEE) is among the fastest growing types of solid waste in the world. In addition, this is a complex waste stream when it comes to recycling, due to the large variety of valuable ...
Reação de redução de compostos nitrogenados: de aspectos fundamentais em monocristais de Pt à utilização de nanopartículas bimetálicas
(Universidade Federal de São Carlos, 2022-02-23)
Because of the high consumption of nitrogen-based compounds by both industry and agriculture, there is an imbalance in nitrogen cycle and the nitrate and nitrite reduction reaction can be a solution. These processes are ...
Complexos de Pd(II) e Pt(II) contendo tiossemicarbazonas derivadas do tiofeno: síntese, caracterização, investigação da citotoxicidade e modo de ação
(Universidade Federal de São Carlos, 2022-03-16)
In this work, ten ligands and four palladium and two platinum complexes containing thiosemicarbazones derived from thiophene were synthesized in order to evaluate their cytotoxic profile against tumor cells. The compounds ...
Propriedades citotóxicas e mecanismo de ação de novos complexos fosfínicos de rutênio(II) contendo ligantes naftoquinonas
(Universidade Federal de São Carlos, 2022-12-15)
In this study, two series of ruthenium(II)-phosphine complexes containing naphthoquinone ligands were synthesized, characterized, and investigated regarding the cytotoxic activity. The first series represents the compounds ...
Performance optimization in redox flow batteries: a computational approach
(Universidade Federal de São Carlos, 2022-02-22)
Redox flow batteries (RFBs) emerge as an alternative technology for the storage of energy on a large scale. The main characteristics of this type of device are related to its unique design, which provides scalability, ...
Esfoliação e funcionalização de nanofolhas de MoS2: desenvolvimento de novos materiais elastoméricos
(Universidade Federal de São Carlos, 2021-09-30)
Two-dimensional materials, such as MoS2, have been extensively studied in recent decades due to their excellent properties in electronics, electrocatalysis, optics and mechanics. A major focus in recent research resides ...
Estudo teórico e experimental da interação de elétrons com moléculas de interesse astroquímico
(Universidade Federal de São Carlos, 2021-09-08)
We performed a theoretical and experimental investigation on electron (e⁻) scattering by molecules of astrochemical interest. Theoretically, we obtained elastic differential (DCSs), integral (ICSs) and momentum-transfer ...
Degradação forçada dos fármacos nitazoxanida e sofosbuvir e degradação térmica de dispersões sólidas amorfas contendo ritonavir
(Universidade Federal de São Carlos, 2022-04-28)
The first chapter of this work aimed to use design of experiments in the forced degradation of sofosbuvir (SOF) and nitazoxanide (NTZ). The variables pH, temperature and interaction between temperature and H2O2 contributed ...