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Funcionalização de 5-iodo-1,2,3-triazóis e síntese de seleno- e tioésteres por meio de reações de acoplamento carbonilativo empregando monóxido de carbono gerado ex situ
(Universidade Federal de São Carlos, 2022-06-06)
The use of pressurized carbon monoxide (CO) gas cylinders can lead to serious risks during their handling. Hence, the demand for safer carbonylation methods has been gradually increasing with the use of different techniques ...
Photoredox-mediated aminoalkylation and carbamoylation of azomethine imines
(Universidade Federal de São Carlos, 2021-08-25)
Over the past decade, the organic synthetic community has witnessed the emergence of a new and complementary approach to the conventional radical chemistry. Photochemistry has proven to be a powerful and more sustainable ...
Síntese de compostos N-heterocíclicos via fotocatálise
(Universidade Federal de São Carlos, 2022-03-18)
Heterocycles belong to a privileged class of organic compounds that play a
prominent role in chemistry and biology. There is an extensive literature about
methodologies for the synthesis of these substances, showing their ...
Síntese, caracterização e estudo catalítico de complexos miméticos das enzimas Nitrito Redutase e Anidrase Carbônica
(Universidade Federal de São Carlos, 2022-03-30)
Metalloenzymes are efficient biological catalysts that inspire the creation of coordination compounds that mimic their active site. In this work, the synthesized complexes were inspired by two enzymes: Nitrite Reductase ...
Desenvolvimento de novas tecnologias baseadas em materiais biocidas
(Universidade Federal de São Carlos, 2021-08-13)
The worldwide outbreak of the coronavirus pandemic (COVID-19) and other emerging microbial infections have attracted particular interest in the design and development of new biocidal agents with a broad spectrum of activity. ...
Conhecimentos docentes e tecnologias digitais: perspectivas para a formação do professor de Química
(Universidade Federal de São Carlos, 2021-08-02)
The present research was conducted through a formative pedagogical intervention work promoting the insertion of digital tools articulated to the teaching of content and pedagogical practices to undergraduate students of a ...
Explorando reações de funcionalização C(sp2)-H fotocatalisadas por porfirinas em condições de fluxo contínuo e o uso da eletrocatálise para promover acoplamentos C-S
(Universidade Federal de São Carlos, 2021-06-28)
Photoarylation reactions (Chapter I) were studied in both batch and continuous flow conditions starting from arenodiazonium salts and activated olefins to yield α-aryl ketones/aldehyde derivatives. Such reactions were ...
Estudos mecanísticos de reações de cicloadição e ciclização através de ferramentas experimentais e teóricas
(Universidade Federal de São Carlos, 2022-02-22)
Part 1: The 1,3-dipolar cycloaddition of nitroolefin and azides have emerged as an important approach for the synthesis of 1,2,3-triazole. We describe the rationalization of the regioselectivity/reactivity trends of this ...
Síntese de heterociclos nitrogenados através de reações de funcionalização C-H de azaarenos e avaliação da atividade antiparasitária
(Universidade Federal de São Carlos, 2022-01-28)
The neglected diseases caused by parasites, such as Chagas´ disease, sleeping sickness and leishmaniasis, affect thousands of people every year, mainly in tropical and underdeveloped countries. Due to the lack of efficient ...
Estudo da resposta de tecidos de Citrus sinensis em fases ontogenéticas distintas à infecção por Candidatus Liberibacter asiaticus
(Universidade Federal de São Carlos, 2021-06-29)
The objective was to develop analytical methods to evaluate the variation in the chemical profile between specimens of juvenile and mature tissues of Pera orange (C. sinensis) in cuttings and grafted on Rangpur lime (C. ...