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Catalisadores à base de Cu, Zn, Al e Ce aplicados à reação deslocamento gás-água
(Universidade Federal de São Carlos, 2014-03-26)
The water gas-shift reaction (WGS) is an important step in the production process and purification of H2 from hydrocarbon. Commercially, to overcome the thermodynamic and kinetic limitations, this reaction occurs in two ...
Estudo da oxidação preferencial do CO por catalisadores a base de irídio
(Universidade Federal de São Carlos, 2014-03-31)
Ir/Al2O3 samples were prepared to evaluate the influence of the particle size of the metal in the preferential oxidation of CO reaction. Initially, samples with different amounts of iridium were prepared in an attempt to ...
Propriedades eletrônicas e estruturais do Cu/ZrO2 aplicadas à reação do etanol
(Universidade Federal de São Carlos, 2012-06-22)
Copper is a typical catalyst for dehydrogenation of ethanol to acetaldehyde. However, copper supported on ZrO2 was found to be extremely active and selective to convert ethanol directly to ethyl acetate. Several reports ...
Estudos sobre a síntese da zeólita Beta na presença de íons fluoreto
(Universidade Federal de São Carlos, 2013-02-27)
One alternative to increase the octane rating of gasoline without the use of toxic or polluting compounds, banned by environmental legislation, is the transformation of linear paraffins of low octane number into branched ...
Zéolitas ZSM-12 mesoporosas textura, cristalinidade e atividade ácida para o craqueamento de cicloexano
(Universidade Federal de São Carlos, 2013-09-12)
The research addressed the generation of mesoporosity in the zeolite ZSM-12 (MTW). In the first part we studied the synthesis of ZSM-12 via conventional methodology and in the presence of a mesopore directing agent, ...
Catalisadores à base de CuO, Fe2O3 ou CuO-Fe2O3 suportados sobre y-Al2O3, ZrO2 ou ZrO2/y-Al2O3 para a redução de NO com CO
(Universidade Federal de São Carlos, 2014-03-31)
NO, NO2 and N2O nitrogen oxides, named NOx, strongly contribute to the air pollution and to minimize their emissions are used catalytic processes. The catalytic reduction of NO with CO has the advantage to simultaneously ...
Reforma a vapor do ácido acético sobre catalisadores de Ni/Al2O3: estudo das rotas reacionais
(Universidade Federal de São Carlos, 2014-02-21)
Acetic acid (AA), one majority substance contained in the bio-oil from biomass pyrolysis, was used as a model molecule for study of reaction routes of steam reforming on Ni/θ-Al2O3 catalysts. The catalyst containing ...
Avaliação do catalisador CTA-MCM-41, modificado por poliacrilatos, na transesterificação de monoéster
(Universidade Federal de São Carlos, 2014-03-24)
The silica hybrid CTA-MCM-41 (where CTA is the cetyltrimethylammonium cation) was synthesized and used in the transesterification of ethyl acetate with methanol. This is a model reaction used to test basic catalysts for ...
Reforma a vapor do etanol sobre catalisadores de Ni e Co suportados
(Universidade Federal de São Carlos, 2004-08-17)
The Ni and Co catalysts supported on Al2O3 and 12%La-Al2O3 and the carrier 12%La-Al2O3 were prepared by impregnation of the support with an aqueous solution of corresponding nitrates metals. The catalysts were characterized ...
Aproveitamento de CO2 para a produção de metanol e compostos C2+ aplicando catalisadores à base de Cu e Fe
(Universidade Federal de São Carlos, 2021-08-10)
Considering the approaches to use of the CO2, this work aimed to study CO2 hydrogenation at gas phase and CO2 reduction (CO2RR) via electrocatalysis. Through these methodologies a wide variety of value-added products can ...