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Sobre a estabilidade de catalisadores de cobalto suportados durante a reforma do etanol
(Universidade Federal de São Carlos, 2012-06-11)
Cobalt-based catalysts supported on γ-alumina and magnesium aluminate modified with lanthanum and cerium have been applied to various conditions of reforming of ethanol. The initial challenge was to control the rate ...
Catalisadores derivados de óxidos do tipo perovskita LaMO3, LaMFeO3 e LaMO3/γ-Al2O3 (M = Co, Ni ou Fe) aplicados à reforma a vapor de etanol
(Universidade Federal de São Carlos, 2014-07-30)
The hydrogen production has been extensively studied as a clean and powerful energy source, indicating that in the future hydrogen will became a key component for the global energy production, since burning fossil fuels, ...
Óxidos mistos de magnésio e alumínio contendo lítio e cálcio como catalisadores para transesterificação etílica
(Universidade Federal de São Carlos, 2013-03-08)
This work deals with the investigation on the production of heterogeneous catalysts of base surface properties applied for ethylic transestérification, aiming the biodiesel production. In the first and second chapters of ...
Efeito do teor de CeO2 em catalisadores de Pt/CeO2-Al2O3 para as reações de oxidação parcial e reforma do metano.
(Universidade Federal de São Carlos, 2005-03-10)
The effect of CeO2 loading in Pt/CeO2-Al2O3 catalysts was investigated. Pt
catalysts supported on mixed CeO2-Al2O3 carriers with different CeO2 loading 1,
3, 6, 12, 20 wt.% were prepared by incipient wetness impregnation ...
Estudo de catalisadores de cobre suportados para a reação de oxidação preferencial do CO
(Universidade Federal de São Carlos, 2010-06-30)
The CO preferential oxidation reaction (PROX-CO) has been widely studied in last few years. Aiming H2 purification for proton-exchange membrane cells (PEMFC) use, the main role of the PROX-CO reaction should be reduce the ...
Preparação e aplicação de óxidos tipo perovskita La1-xCexNiO3 e La1-xCaxNiO3 para obtenção de gás de síntese a partir do metano.
(Universidade Federal de São Carlos, 2006-04-20)
Catalysts precursors with perovskite structure like La1-xCexNiO3 ( x = 0,
0.03, 0.05, 0.1, 0.4 ,0.7) and La1-xCaxNiO3 (x = 0, 0.05, 0.1, 0.3, 0.5, 0.8) have
been prepared by three different methods: precipitation, citrate ...
Nanopartículas de Co suportadas em SiO2: síntese, caracterização e propriedades catalíticas para a reforma a vapor do etanol
(Universidade Federal de São Carlos, 2007-03-16)
Colloidal Co Nanoparticles (Co-NPs) were used to prepare supported Co catalysts. The Co-
NPs were obtained by thermal decomposition of the precursor Co2(CO)8 in the presence of
oleic acid and trioctylphosphine oxide ...
Efeito das condições de preparação da [CTA+]-SiMCM-41 na atividade da transesterificação
(Universidade Federal de São Carlos, 2010-02-26)
The hybrid [CTA+]-SiMCM-41 mesoporous material (where CTA+ is the cetyltrimethylammonium cation) was employed as synthesized in the transesterification reaction between ethyl acetate and methanol. This is a model reaction ...
Desenvolvimento de catalisadores para reforma e oxidação combinadas do metano
(Universidade Federal de São Carlos, 2009-03-20)
In this work, we studied the effects of the promoters of support (ZrO2, La2O3, CeO2, CeO2-ZrO2, CeO2-ZrO2-La2O3 and La2O3) in the nickel catalysts supported on γ-Al2O3 were studied. The supports were prepared by wet ...
Sólidos micro-mesoestruturados tipo zeólita ZSM-5/peneira molecular MCM-41 - síntese e estudo de propriedades.
(Universidade Federal de São Carlos, 2006-08-16)
In the transformation of bulky molecules, the necessity of catalysts that allow the diffusion to and from the active sites located in the interior of the porous system has become of higher interest. The restriction for the ...