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Formação de mesoporos na síntese de zeólitas ZSM-5 via nanomoldagem avaliação no craqueamento de n-decano
(Universidade Federal de São Carlos, 2008-04-04)
The use of zeolites in the cracking of hydrocarbons is limited because the molecules higher than 0.74 nm do not diffuse in their micropores. In the other hand, molecular sieves as MCM-41, MCM-48 ou SBA-15, whose diameters ...
Reforma a vapor do ácido acético sobre catalisadores de Ni/Al2O3: estudo das rotas reacionais
(Universidade Federal de São Carlos, 2014-02-21)
Acetic acid (AA), one majority substance contained in the bio-oil from biomass pyrolysis, was used as a model molecule for study of reaction routes of steam reforming on Ni/θ-Al2O3 catalysts. The catalyst containing ...
Propriedades eletrônicas e estruturais do Cu/ZrO2 aplicadas à reação do etanol
(Universidade Federal de São Carlos, 2012-06-22)
Copper is a typical catalyst for dehydrogenation of ethanol to acetaldehyde. However, copper supported on ZrO2 was found to be extremely active and selective to convert ethanol directly to ethyl acetate. Several reports ...
Catalisadores à base de Cu, Zn, Al e Ce aplicados à reação deslocamento gás-água
(Universidade Federal de São Carlos, 2014-03-26)
The water gas-shift reaction (WGS) is an important step in the production process and purification of H2 from hydrocarbon. Commercially, to overcome the thermodynamic and kinetic limitations, this reaction occurs in two ...
Estudos sobre a síntese da zeólita Beta na presença de íons fluoreto
(Universidade Federal de São Carlos, 2013-02-27)
One alternative to increase the octane rating of gasoline without the use of toxic or polluting compounds, banned by environmental legislation, is the transformation of linear paraffins of low octane number into branched ...
Catalisadores à base de CuO, Fe2O3 ou CuO-Fe2O3 suportados sobre y-Al2O3, ZrO2 ou ZrO2/y-Al2O3 para a redução de NO com CO
(Universidade Federal de São Carlos, 2014-03-31)
NO, NO2 and N2O nitrogen oxides, named NOx, strongly contribute to the air pollution and to minimize their emissions are used catalytic processes. The catalytic reduction of NO with CO has the advantage to simultaneously ...
Formação de mesoporosidade em zeólitas ZSM-5: avaliação do método de preparação e do potencial como catalisador ácido através do craqueamento de cicloexano
(Universidade Federal de São Carlos, 2012-04-27)
Due to their potential as acid catalyst and hydrothermal stability, USY, ZSM-5 and modernite zeolites are widely used in several processes of petroleum refining and petrochemical industries. With the discovery of new ...
Síntese e avaliação catalítica das zeólitas com estrutura BEA, MFI e MTW na reação de Knoevenagel
(Universidade Federal de São Carlos, 2014-08-22)
The use of zeolites in basic catalysis is small, especially when compared to the numerous applications of material in their acid form. Inside this context, are even smaller the number of studies on the use of as-synthesized ...
Estudo da oxidação preferencial do CO por catalisadores a base de irídio
(Universidade Federal de São Carlos, 2014-03-31)
Ir/Al2O3 samples were prepared to evaluate the influence of the particle size of the metal in the preferential oxidation of CO reaction. Initially, samples with different amounts of iridium were prepared in an attempt to ...
Zéolitas ZSM-12 mesoporosas textura, cristalinidade e atividade ácida para o craqueamento de cicloexano
(Universidade Federal de São Carlos, 2013-09-12)
The research addressed the generation of mesoporosity in the zeolite ZSM-12 (MTW). In the first part we studied the synthesis of ZSM-12 via conventional methodology and in the presence of a mesopore directing agent, ...