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Seleção de suportes e protocolos de imobilização de lipases para a síntese enzimática de biodiesel
(Universidade Federal de São Carlos, 2009-05-25)
The objective of this thesis was to prepare and select immobilized lipase derivatives with high catalytic activity and thermal stability to mediate the biodiesel synthesis from palm and babassu oils by ethanolic route. The ...
Hidrodinâmica e transferência de oxigênio em três biorreatores Airlift de circulação interna geometricamente semelhantes
(Universidade Federal de São Carlos, 2009-03-12)
Internal-loop airlift reactors (ALR) are a special class of pneumatic reactors. The use of this type of reactor has been attractive for chemical and biological reactions because of their simple construction without moving ...
Modelo matemático do processo de purificação do ácido clavulânico por troca iônica em coluna de leito fixo
(Universidade Federal de São Carlos, 2009-08-04)
Clavulanic acid (CA) is a β-lactam antibiotic produced industrially by submerged cultures of the filamentous bacterium Streptomyces clavuligerus. Due to its importance, several studies on the purification of clavulanic ...
Estudo do efeito da adição de Au, Pd e Pt em catalisadores Cu/CeO2 aplicados à reação de deslocamento gás-água a baixa temperatura
(Universidade Federal de São Carlos, 2008-07-02)
Cu/CeO2 catalysts doped with Au, Pd or Pt (WGSR) were prepared and applied in water gas shift reaction. The CeO2 support was prepared by four different way: urea co-precipitation-gelation (CeO2-UGC), hydrothermal method ...
Aplicação de peneiras moleculares contendo cátions orgânicos em catálise básica
(Universidade Federal de São Carlos, 2008-12-12)
This thesis was aimed at studying novel basic catalysts based on molecular sieves containing alkylammonium cations. The studied molecular sieves were faujasite zeolites (FAU) and mesoporous silicate (like MCM-41). The ...
Avaliação de aspectos fluidodinâmicos e da transferência de calor em leito fixo com escoamento gás-líquido concorrente vertical.
(Universidade Federal de São Carlos, 2004-03-02)
In this work, the heat transfer in packed bed with gas-liquid co-current downflow and upflow was investigated. The influence of hydrodynamic factors, of the size and shape of particles, of the length of the thermal section ...
Sistema automático de supervisão e controle de cultivos de alta densidade celular de E. coli recombinante
(Universidade Federal de São Carlos, 2011-12-22)
High cell density cultivations of recombinant E. coli are a fast and economical way to produce recombinant proteins. Through this bioprocess, products with high added value and pharmaceuticals of great importance such as ...
Busca heurística e inferência de parâmetros cinéticos de reações de hidrotratamento de óleo diesel a partir de dados experimentais escassos
(Universidade Federal de São Carlos, 2011-06-30)
Currently, the amount of contaminants (such as sulfur, nitrogen and aromatics) in diesel oil is strictly controlled, due to their impact on pollutant emissions. The most important process used to meet fuel specifications ...
Nanopartículas de Pt suportadas em Al2O3 e CeO2-Al2O3: síntese e caracterização de catalisadores aplicados à reação de deslocamento gás-água
(Universidade Federal de São Carlos, 2011-04-28)
Colloidal Pt nanoparticles were synthesized according to an adapted procedure from Song and co-workers [1], which it was based on the reduction of dihydrogen hexachloroplatinate by ethylene glycol in a basic solution, but ...
Operação periódica de um leito gotejante de carvão ativado para redução da emissão do poluente atmosférico SO2 com geração de ácido sulfúrico.
(Universidade Federal de São Carlos, 2003-06-23)
A laboratory-scale investigation of SO2 scrubbing was carried out in a 77.92mm (diameter) × 80.00mm trickle bed with 2.00-2.36mm activated carbon particles using continuous and periodically interrupted liquid flows. The ...