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Avaliação das propriedades química e citotóxicas de novos compostos organometálicos de Ru(II) com aciltioureias
(Universidade Federal de São Carlos, 2018-08-16)
This thesis shows a study based on the synthesis, characterization and biological evaluation of 19 new organometallic Ru(II) complexes with acylthioureas. The complexes have general formula Ru(6-p-cymene)Cl(PPh3)Tu]PF6 e ...
Desenvolvimento de potenciais metalofármacos de rutênio contendo 1,1’-bis(difenilfosfino)ferroceno e ligantes mercapto
(Universidade Federal de São Carlos, 2019-02-25)
The antimetastatic activity, high selectivity and cytotoxicity in various human tumor cell line makes ruthenium (II) complexes attractive for the development of new chemotherapeutic agents for cancer treatment. In this ...
Sobre a influência de fosfinas e do ligante isocianida de p-Toluenosulfonilmetila na citotoxicidade de compostos de Ru(II)
(Universidade Federal de São Carlos, 2018-08-17)
The main objective of the present work was to obtain new Ru(II) complexes with lingans diimino, phosphinic and isocyanide p-toluenesulfonylmethyl, to characterize them by diverse physical and spectroscopic techniques, to ...
Estudo químico de plantas do gênero Hortia, do fungo Guignardia citricarpa e avaliação de seus potenciais efeitos biológicos
(Universidade Federal de São Carlos, 2011-10-26)
The chemical investigation of plants belonging to the genus Hortia described here aimed at contributing to the chemosystematics of the family Rutaceae as well as to the correct placement of this genus within this family. ...
Estudo fitoquímico e quimiossitemático de Galipea, Swinglea (Rutaceae) e avaliação do potencial biológico dos compostos isolados
(Universidade Federal de São Carlos, 2011-06-07)
The Galipea genus species classifications has been confuse since genus classification. Showing no agreement among taxonomists in several classification systems since 1823. However, Kallunki & Pirani corrected errors ...
Estudos sobre a fotodegradação de poluentes catalisada por semicondutores: avaliação do papel do dopante nitrogênio na atividade de TiO2
(Universidade Federal de São Carlos, 2013-04-12)
The photodegradation of organic pollutants in water, catalyzed by semiconductors, is an important and well-known area but it is still necessary develop new materials showing visible photoactivity, in order to take advantage ...
Análise da interação molecular proteína-herbicida através de simulação computacional: aplicação no desenvolvimento de nanobiossensores
(Universidade Federal de São Carlos, 2013-04-29)
In this study, our goal was evaluate the interactive forces between the Atomic force microscope tip (AFM tip) and an important enzyme responsible to fatty acids synthesis in all living beings (Acetyl CoA Carboxylase - fic ...
Produção e caracterização de material de referência de forrageira para nutrientes e contaminantes inorgânicos
(Universidade Federal de São Carlos, 2013-04-12)
The main aim of this work was to produce a candidate material for national reference material, the forage Brachiaria brizantha Stapf. cv. Marandu, containing known levels of contaminants (Cr, Pb, Cd, and As) and macro and ...
Applications of NMR techniques: Hyphenations (LC-SPENMR), affinity (DOSY) and NOE based (STD and Tr-OESY) to probe the binding interactions of ligands (synthetic and natural) towards protein
(Universidade Federal de São Carlos, 2014-01-17)
O foco principal desse trabalho foi a implementação, otimização e aplicações práticas de métodos de ressonância magnética nuclear (RMN) com o propósito de avaliar as interações entre moléculas de diferentes massas molares, ...
Preparação e caracterização das propriedades luminescentes de blendas de poli(3-ácidotiofenoacético) com acetato de celulose ou poli(vinil álcool)
(Universidade Federal de São Carlos, 2010-11-19)
We have studied the optical properties of Poly(3-Thiopheneacetic Acid) (PTAA) by absorption, emission, and infrared measurements. We have observed, on the contrary of what broadly reported in the literature, that the ...