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Fotocatálise e suas aplicações em reações de ciclização oxidativa e terapia fotônicas
(Universidade Federal de São Carlos, 2019-05-06)
In the chapter 1, studies on photocatalysed reactions were carried out by porphyrins and other photocatalysts aiming at the formation of radicals in amino aromatic systems for subsequent addition reaction. More specifically, ...
Metátese de fechamento de anel: espiro-anelação estereosseletiva / Reações multicomponentes de Diels-Alder na síntese de compostos tricíclicos
(Universidade Federal de São Carlos, 2011-02-22)
In this work, a study of different synthetic ways was made in order to obtain spiro compounds starting from R-(-)-carvone, getting to the formation of cycloheptenone as an intermediate, which undergoes two consecutives ...
Análise dos constituintes fixos e voláteis de fungos endofíticos dos gêneros Penicillium e Xylaria e de suas plantas hospedeiras
(Universidade Federal de São Carlos, 2010-10-08)
Was conducted the study of chemical constituents volatiles and fixed of endophytes fungi. For this, we used the Penicillium griseoroseum, Penicillium brasilianum, Xylaria (NICL3) and different species of the genus Trichoderma, ...
Estratégias de desreplicação aplicadas ao estudo da planta Alternanthera brasiliana e dos fungos endofíticos associados
(Universidade Federal de São Carlos, 2011-02-24)
Alternanthera brasiliana is widely used by Brazilian people as a folk medicine for the treatment of numerous diseases. However, little is known about its chemical composition and the microorganisms that live in association ...
Precessão Livre de Onda Contínua (CWFP) como ferramenta para supressão do sinal de solvente em RMN de alta resolução
(Universidade Federal de São Carlos, 2011-08-01)
The application of Continuous Wave Free Precession (CWFP) method for solvent suppression in high resolution NMR spectroscopy is reported. The applied methodology was based in the use of conventional pulse sequence that use ...
Tris(trimethylsilyl)silane and visible-light irradiation : a new metal- and additive-free photochemical process for the synthesis of indoles and oxindoles
(Universidade Federal de São Carlos, 2016-07-29)
A combined tris(trimethylsilyl)silane and visible-light-promoted intramolecular reductive cyclization protocol for the synthesis of indoles and oxindoles has been developed (Scheme 1).1 This straightforward and efficient ...
Complexos de rutênio contendo lapachol e lausona: síntese, caracterização e suas propriedades quimioterapêuticas
(Universidade Federal de São Carlos, 2014-03-21)
The present work focuses on the synthesis and characterization of
new ruthenium complexes containing the naphthoquinones lapachol and
lawsone, due to the interesting biological properties exhibited by them.
Complexes ...
Multicomponent approach to silica-grafted peptide catalysts : A 3 D continuous-flow organocatalytic system with on-line monitoring of conversion and stereo-selectivity
(Universidade Federal de São Carlos, 2014-11-28)
The derivatization of organocatalysts with functional appendages suitable to anchor onto solid supports is usually achieved by stepwise syntheses. As an alternative to such a strategy, this work describes a one-pot approach ...
Caracterização química por cromatografia líquida e análise quimiométrica de espécies vegetais de Bauhinia com aplicação em controle de qualidade de amostras comerciais de "pata-de-vaca"
(Universidade Federal de São Carlos, 2011-07-27)
Chemical characterization by liquid chromatography and chemometric analysis of Bauhinia species (popularly known as pata-de-vaca ) with applications in quality control of commercial samples. The infusion of leaves from ...
Técnicas de bioinformática aplicadas ao estudo de poligalacturonases de fungos
(Universidade Federal de São Carlos, 2012-04-18)
Plant cell walls are composed of approximately 65% cellulose microfibrils and pectin. The latter is proteolytically degraded by the so-called pectinases enzymes (also known as pectinolytic enzymes). Pectinases may be either ...