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Ligação covalente coordenada boro-nitrogênio : um estudo comparativo entre moléculas derivadas do etano, eteno e etino orgânicos e inorgânicos
(Universidade Federal de São Carlos, 2016-12-06)
This work consists in the theoretical analysis and comparison of some
organic compounds and its similar inorganics, through the change of the BN pair,
and, in some cases, the BP pair, in the place of CC pair. First, ...
Instabilidades em eletrocatálise: cinética complexa catalisada por superfícies modelo
(Universidade Federal de São Carlos, 2018-02-28)
The electro-oxidation of small molecules is an area of great interest due to its application in energy converting systems, such as fuel cells. The reactions present in these systems involve several reaction pathways - which ...
Síntese, caracterização e estudos de citotoxicidade e alvo biológico de complexos quadráticos planos contendo Tiossemicarbazonas
(Universidade Federal de São Carlos, 2019-09-20)
The diversity of cancer diseases and the side effects caused by the drugs commonly used in cancer treatment require different antineoplasic agents able to operate more specific and in a way to minimize the side effects. ...
Estudo de alterações metabólicas nos fungos endofíticos Penicillium brasilianum e Penicillium griseoroseum
(Universidade Federal de São Carlos, 2011-08-26)
Microorganisms, known as being relatively simple, have shown a great adaptation power to different nutritional situations by changing their metabolism with lack or supply of nutrients in the culture medium. This feature ...
Uso de imagens digitais e ferramentas quimiométricas para identificação e determinação de Cr (VI) em solos contaminados
(Universidade Federal de São Carlos, 2012-03-23)
The determination of toxic metals in soils is an important factor to access their quality or identify possible contamination. The element Cr has double feature: Cr (III) is essential for human beings and Cr (VI) is toxic. ...
Preparação, caracterização e aplicação de eletrodos de nanotubos de carbono na determinação de Cr(III), Cr(VI) e flavonoides
(Universidade Federal de São Carlos, 2013-01-30)
The objective of this work is the development of a carbon nanotubes past electrode (CNTs) as electrochemical sensors in the analysis of flavonoids, (+) catechin and rutin, and Cr (III) and Cr (VI) ions, by differential ...
Estudo teórico computacional dos sistemas micelares de alquilbenzenos em diiodometano
(Universidade Federal de São Carlos, 2014-02-28)
The surfactant-like behavior of the alkylbenzenes in diiodomethane is experimentally verified, being observed, in addition to the characteristic effects on the surface tension, evidences of clusters formation. The main ...
Desenvolvimento de nanocompósitos baseados em hidrogéis aplicados à liberação de nutrientes agrícolas
(Universidade Federal de São Carlos, 2014-03-21)
Nanocomposites were developed based on polyacrylamide hydrogels (PAAm) and methylcellulose (MC) reinforced with montmorillonite (MMT), undergoing the materials to subsequent hydrolysis process and evaluating their loading ...
Síntese de acil fosfodiésteres por mecanoquímica: uma metodologia de química verde
(Universidade Federal de São Carlos, 2019-08-22)
Green chemistry is very concerned with the sustainability of chemical reactions, where one of the objectives, which in the formulation/remodeling of synthetic routes can replace toxic solvents with solvents of lower toxicity, ...
Determinação de molibdênio em plantas combinando microextração e espectrometria de absorção atômica em chama
(Universidade Federal de São Carlos, 2012-08-16)
In this study, a procedure for the determination of low concentrations of molybdenum in plants by flame atomic absorption spectrometry (FAAS) was developed. The poor sensitivity of FAAS for determination of refractory ...