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Now showing items 11-20 of 22
Síntese e propriedades da zeólita FAU com cristais nanométricos
(Universidade Federal de São Carlos, 2010-07-21)
The FAU zeolite was obtained using different amounts of water. Both at higher levels as the lowest amount of water the intensities of the diffraction peaks are less intense. The results of physisorption of these samples ...
Catalisadores bimetálicos Pt-Fe/CeO2 para a reação de oxidação preferencial do CO
(Universidade Federal de São Carlos, 2010-03-31)
The objective of this work is to study the preferential oxidation (PROX) of carbon monoxide in H2-rich feed streams over Pt-Fe/CeO2 catalysts in a feed gas composed of 3% CO, 1.5% O2, 80% H2, and N2 (for balance). The ...
Síntese da sílica MCM-41 usando um surfactante catiônico polimerizável e avaliação na transesterificação catalítica
(Universidade Federal de São Carlos, 2014-02-20)
The masters work presented is result of a great effort provided by the group, which has worked with changes in the synthesis of CTA-MCM-41. The synthesis of the M41S family (composed of mesoporous silica MCM-41, MCM-48 and ...
Estudos sobre a síntese da zeólita Beta na presença de íons fluoreto
(Universidade Federal de São Carlos, 2013-02-27)
One alternative to increase the octane rating of gasoline without the use of toxic or polluting compounds, banned by environmental legislation, is the transformation of linear paraffins of low octane number into branched ...
Catalisadores à base de CuO, Fe2O3 ou CuO-Fe2O3 suportados sobre y-Al2O3, ZrO2 ou ZrO2/y-Al2O3 para a redução de NO com CO
(Universidade Federal de São Carlos, 2014-03-31)
NO, NO2 and N2O nitrogen oxides, named NOx, strongly contribute to the air pollution and to minimize their emissions are used catalytic processes. The catalytic reduction of NO with CO has the advantage to simultaneously ...
Reforma a vapor do ácido acético sobre catalisadores de Ni/Al2O3: estudo das rotas reacionais
(Universidade Federal de São Carlos, 2014-02-21)
Acetic acid (AA), one majority substance contained in the bio-oil from biomass pyrolysis, was used as a model molecule for study of reaction routes of steam reforming on Ni/θ-Al2O3 catalysts. The catalyst containing ...
Catalisadores à base de Cu, Zn, Al e Ce aplicados à reação deslocamento gás-água
(Universidade Federal de São Carlos, 2014-03-26)
The water gas-shift reaction (WGS) is an important step in the production process and purification of H2 from hydrocarbon. Commercially, to overcome the thermodynamic and kinetic limitations, this reaction occurs in two ...
Estudo da oxidação preferencial do CO por catalisadores a base de irídio
(Universidade Federal de São Carlos, 2014-03-31)
Ir/Al2O3 samples were prepared to evaluate the influence of the particle size of the metal in the preferential oxidation of CO reaction. Initially, samples with different amounts of iridium were prepared in an attempt to ...
Catalisadores de Fe2O3, NiO e Fe2O3 - NiO Suportados in situ em Ce0,5Zr0,5O2 e Ce0,2Zr0,8O2 – Avaliação na Redução de NO com CO
(Universidade Federal de São Carlos, 2014-03-28)
The increasing use of fossil fuels in combustion enginees and power generation plants
has caused a large increase in the emission of sulfur oxides, nitrogen oxides (NOx)
and carbon monoxide into the atmosphere which ...
Formação de mesoporos na síntese de zeólitas ZSM-5 via nanomoldagem avaliação no craqueamento de n-decano
(Universidade Federal de São Carlos, 2008-04-04)
The use of zeolites in the cracking of hydrocarbons is limited because the molecules higher than 0.74 nm do not diffuse in their micropores. In the other hand, molecular sieves as MCM-41, MCM-48 ou SBA-15, whose diameters ...