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Influência da presença de líquidos iônicos no comportamento térmico, termo-mecânico e nas propriedades de transporte em membranas de policarbonato obtidas via casting
(Universidade Federal de São Carlos, 2014-02-25)
New alternatives to the use of polymeric membranes as solid electrolyte in fuel cells have been considered , in order to find solutions to recurrent obstacles that limit the performance of these cells, the dependence of ...
Determinação de Cd, Co, Cr, Cu, Ni e Pb em cosméticos infantis empregando técnicas espectroanalíticas
(Universidade Federal de São Carlos, 2014-07-18)
In this study were developed two methods for sample preparation: one for children s eye shadow and another for chidren s lipstick. In the optimizing process, variables such as nitric acid concentration (2 or 7 mol L-1), ...
Estudo do efeito do envelhecimento eletroquímico em filmes de poli(3-hexiltiofeno)
(Universidade Federal de São Carlos, 2014-10-24)
The study of the electrochemical aging of conductive polymers, including of polythiophenes, has been described in the literature. However, this paper proposed study, in addition to electrochemical aging of polyethylene ...
Multicomponent approach to silica-grafted peptide catalysts : A 3 D continuous-flow organocatalytic system with on-line monitoring of conversion and stereo-selectivity
(Universidade Federal de São Carlos, 2014-11-28)
The derivatization of organocatalysts with functional appendages suitable to anchor onto solid supports is usually achieved by stepwise syntheses. As an alternative to such a strategy, this work describes a one-pot approach ...
Avaliação da espectroscopia Raman intensificada por superfície em papel filtro e métodos quimiométricos na quantificação de fármacos
(Universidade Federal de São Carlos, 2014-02-21)
Raman spectroscopy has been widely used for pharmaceutical analysis in recent decades due to advances of this technique, related to the development of electronics, optics and fundamental studies. As a consequence to the ...
Nanotecnologia verde em uma perspectiva CTSA: análise de uma proposta didática WebQuest para a alfabetização científica na educação básica
(Universidade Federal de São Carlos, 2014-09-15)
The objective of this work was to evaluate the teaching resource WebQuest and the topic of green nanotechnology in order to promote scientific and technological literacy in basic education. Specifically, we tried to identify ...
Síntese e estudo das propriedades fotoluminescentes e fotocatalíticas dos cristais de Ag2-2xMxWO4, (M = Mg e Zn)
(Universidade Federal de São Carlos, 2014-06-03)
This study aimed to investigate the photoluminescence and photocatalytic properties of the alpha phase of silver tungstate ( α-Ag2WO4 ) doped with Mg and Zn (where M = Mg or Zn and x = 0; 0,01; 0,02; 0,04 ou 0,08). The ...
Complexos de rutênio contendo lapachol e lausona: síntese, caracterização e suas propriedades quimioterapêuticas
(Universidade Federal de São Carlos, 2014-03-21)
The present work focuses on the synthesis and characterization of
new ruthenium complexes containing the naphthoquinones lapachol and
lawsone, due to the interesting biological properties exhibited by them.
Complexes ...
Complexos mono- e bimetálicos de cobre(II) e de cobalto(III) com bases de Schiff tridentadas e tetradentadas: sínteses, caracterizações e estudos em reações catalíticas
(Universidade Federal de São Carlos, 2014-05-20)
This dissertation details the synthesis with satisfactory reaction yields (between 56.3 and 96.5%) of mono- and bimetallic complexes of copper(II) and of cobalt(III), containing as ligands, tridentate and tetradentate ...
Biotransformação de cicloadutos de Diels-Alder por células intactas de Penicillium brasilianum, endofítico de Melia azedarach
(Universidade Federal de São Carlos, 2014-03-27)
Endophytic microorganisms have a great enzymatic potential to biotransformate substances of natural and synthetic origin due to strategies developed during colonization to coexist with the plant in an initial hostile ...