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Desenvolvimento de nanocompósitos baseados em hidrogéis aplicados à liberação de nutrientes agrícolas
(Universidade Federal de São Carlos, 2014-03-21)
Nanocomposites were developed based on polyacrylamide hydrogels (PAAm) and methylcellulose (MC) reinforced with montmorillonite (MMT), undergoing the materials to subsequent hydrolysis process and evaluating their loading ...
Estudo teórico computacional dos sistemas micelares de alquilbenzenos em diiodometano
(Universidade Federal de São Carlos, 2014-02-28)
The surfactant-like behavior of the alkylbenzenes in diiodomethane is experimentally verified, being observed, in addition to the characteristic effects on the surface tension, evidences of clusters formation. The main ...
Complexos de rutênio contendo lapachol e lausona: síntese, caracterização e suas propriedades quimioterapêuticas
(Universidade Federal de São Carlos, 2014-03-21)
The present work focuses on the synthesis and characterization of
new ruthenium complexes containing the naphthoquinones lapachol and
lawsone, due to the interesting biological properties exhibited by them.
Complexes ...
Síntese e estudo das propriedades fotoluminescentes e fotocatalíticas dos cristais de Ag2-2xMxWO4, (M = Mg e Zn)
(Universidade Federal de São Carlos, 2014-06-03)
This study aimed to investigate the photoluminescence and photocatalytic properties of the alpha phase of silver tungstate ( α-Ag2WO4 ) doped with Mg and Zn (where M = Mg or Zn and x = 0; 0,01; 0,02; 0,04 ou 0,08). The ...
Complexos mono- e bimetálicos de cobre(II) e de cobalto(III) com bases de Schiff tridentadas e tetradentadas: sínteses, caracterizações e estudos em reações catalíticas
(Universidade Federal de São Carlos, 2014-05-20)
This dissertation details the synthesis with satisfactory reaction yields (between 56.3 and 96.5%) of mono- and bimetallic complexes of copper(II) and of cobalt(III), containing as ligands, tridentate and tetradentate ...
Investigação do processo de corrosão do aço API 5L_X65 em meio de bicarbonato e cloreto utilizando serie temporal de imagens
(Universidade Federal de São Carlos, 2014-11-21)
The carbon steel corrosion process used at in machines and pipelines of oil fields is mainly attributed to the presence of CO2, and H2S dissolved at solution. These compounds usually can to carry the corrosion type more ...
Estudo químico de Bowdichia virgilioides (Fabaceae) na busca de inibidores seletivos de cisteíno peptidases
(Universidade Federal de São Carlos, 2014-03-31)
This work describes the isolation of bioactive secondary metabolites of the plant
species Bowdichia virgilioides in the search for selective inhibitors of cathepsins K, L
and V. Cathepsins are enzymes that have as primary ...
Multicomponent approach to silica-grafted peptide catalysts : A 3 D continuous-flow organocatalytic system with on-line monitoring of conversion and stereo-selectivity
(Universidade Federal de São Carlos, 2014-11-28)
The derivatization of organocatalysts with functional appendages suitable to anchor onto solid supports is usually achieved by stepwise syntheses. As an alternative to such a strategy, this work describes a one-pot approach ...
Reforma a vapor de acetona sobre catalisadores de Ni e Co/MgAl2O4: efeito das propriedades redox dos reagentes e dos catalisadores nos caminhos de reação
(Universidade Federal de São Carlos, 2014-12-12)
The Steam reforming of Acetone (SRA) reaction was studied on magnesium aluminate (MgAl2O4) supported nickel (Ni) and cobalt (Co) catalysts. The catalysts with 8 wt.% of Ni, Co or Ni-Co were prepared by dry impregnation and ...
Estrutura cristalina e eletrônica do CaS: teoria do funcional de densidade aplicada a modelos periódicos
(Universidade Federal de São Carlos, 2014-02-26)
The incessant search for better materials with diverse applications and increasingly smaller size has been performed by numerous research groups. The calcium sulfide semiconductors have been the focus of study for applications ...